Journal
CHEMSUSCHEM
Volume 11, Issue 18, Pages 3315-3322Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.201801066
Keywords
carbon dioxide; heterogeneous catalysis; metal-organic frameworks; nanoreactors; photocatalysis
Funding
- Deutsche Forschungsgemeinschaft (DFG) [WI 4721/1-1]
- GENCI (CINES/TGCC/IDRIS) [2016-097343]
- PSL University
- French State Program Investissements d'Avenir (Grants LABEX DYNAMO) [ANR-11-LABX-0011]
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A molecular catalyst [Cp*Rh(4,4-bpydc)](2+) and a molecular photosensitizer [Ru(bpy)(2)(4,4-bpydc)](2+) (bpydc=bipyridinedicarboxylic acid) were co-immobilized into the highly porous metal-organic framework MIL-101-NH2(Al) upon easy postsynthetic impregnation. The Rh-Ru@MIL-101-NH2 composite allows the reduction of CO2 under visible light, while exhibiting remarkable selectivity with the exclusive production of formate. This Rh-Ru@MIL-101-NH2 solid represents the first example of MOFs functionalized with both a catalyst and a photosensitizer in a noncovalent fashion. Thanks to the coconfinement of the catalyst and photosensitizer into the cavity's nanospace, the MOF pores are used as nanoreactors and enable molecular catalysis in a heterogeneous manner.
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