Journal
CHEMSUSCHEM
Volume 11, Issue 14, Pages 2310-2314Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.201800488
Keywords
alcohols; homogeneous catalysis; rhodium; ruthenium; tandem reactions
Funding
- Fundacao para a Ciencia e Tecnologia (FCT) [PEst-OE/QUI/UI0313/2014]
- FEDER through the COMPETE [POCI-01-0145-FEDER-016387, H2020 AAC/02/SAICT/2017/027996]
- FCT [PD/BD/114340/2016, RECI/QEQ-QFI/0168/2012, CENTRO-07-CT62-FEDER-002012]
- Evonik Performance Materials GmbH
- State of Mecklenburg-Vorpommern
- Leibniz Association (Leibniz Competition) [SAW-2016-LIKAT-1]
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An active and selective dual catalytic system to promote domino hydroformylation-reduction reactions is described. Apart from terminal, di- and trisubstituted olefins, for the first time the less active internal C-C double bond of tetrasubstituted alkenes can also be utilized. As an example, 2,3-dimethylbut-2-ene is converted into the corresponding n-alcohol with high yield (90%) as well as regio- and chemoselectivity (>97%). Key for this development is the use of a combination of Rh complexes with bulky monophosphite ligands and the Ru-based Shvo's complex. A variety of aromatic and aliphatic alkenes can be directly used to obtain mainly linear alcohols.
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