Journal
CHEMSUSCHEM
Volume 11, Issue 8, Pages 1316-1320Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.201800038
Keywords
alcohols; aqueous hydrogenation; biomass conversion; heterogeneous catalysis; ruthenium
Funding
- Natural Science Foundation of China [21703275]
- Shanxi Provincial Natural Science Foundation of China [201701D221030]
- Program for Sanjin Scholars of Shanxi Province
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A highly efficient and green process was developed for direct conversion of levulinic acid into 1,4-pentanediol over Mo-modified Ru/activated carbon (AC) catalyst in a continuous fixed-bed reactor. The Ru-MoOx/AC catalyst was found to be efficient for the aqueous-phase hydrogenation of levulinic acid to 1,4-pentanediol, whereby a high yield (96.7 mol%) of 1,4-pentanediol was obtained under mild reaction conditions (70 degrees C, 4 MPa H-2).
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