Partition of Zn, Cd, and Pb during co-combustion of sedum plumbizincicola and sewage sludge

Co-combustion of sedum plumbizincicola and sewage sludge was performed in a tubular furnace. The influence of experimental conditions on the partitioning of Zn, Cd, and Pb was investigated. The results showed that 30% sewage sludge was proposed as the optimal ratio for the co-combustion as a compromise between low calorific value and high amount of heavy metal remained in the bottom ash. High temperature increased the volatilization degree of heavy metals, among which the performance of Cd and Pb was obvious than Zn. Rising oxygen concentration was beneficial to the formation of heavy metal compounds, and the effect of oxygen on Zn was the most pronounced. Thermodynamic equilibrium calculation was carried out to forecast heavy metal compounds. The results demonstrated that Zn, Cd, and Pb mainly generated ZnAl2O4, CdSiO3 and PbSiO3 in solid phase, which are partly confirmed by X-ray diffraction (XRD). The promising results offered a great possibility of heavy metal immobilization, indicating the combustion of Sedum plumbizincicola with sewage sludge is an effective way for waste disposal. (C) 2018 Elsevier Ltd. All rights reserved.