4.7 Article

Mesoporous nanoplate multi-directional assembled Bi2WO6 for high efficient photocatalytic oxidation of NO

Journal

CHEMOSPHERE
Volume 193, Issue -, Pages 737-744

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.chemosphere.2017.11.048

Keywords

Photocatalytic oxidation; NOx removal; Bi2WO6; Hierarchical mesoporous architecture

Funding

  1. National Natural Science Foundation of China [21476183, 21676213, 51372201]
  2. China Postdoctoral Science Foundation [2016M600809]
  3. Natural Science Basic Research Plan in Shaanxi Province of China [2017JM2026]
  4. Scientific Research Foundation of Graduate Students of Northwest University [YZZ15003]

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Herein, a mesoporous nanoplate multi-directional assembled Bi2WO6 architecture was successfully prepared and applied for the photocatalytic removal of NOx pollutants at low concentrations under visible light and simulated solar light irradiation. Bi2WO6-180-C synthesized at a hydrothermal temperature of 180 degrees C with calcination exhibited an excellent conversion efficiency in the photocatalytic oxidation of gaseous NO. The crystallinity, morphology, specific surface area, pore environment, light absorption, and separation of photogenerated electrons and holes were investigated by various techniques; the excellent photocatalytic performance of Bi2WO6-180-C was attributed to its special hierarchical mesoporous structure with an appropriate pore size and interconnected porous network, which imparted good gas permeability and fast mass transfer of reaction intermediates and final products of NO oxidation. Furthermore, hierarchical mesoporous Bi2WO6. (C) 2017 Elsevier Ltd. All rights reserved.

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