Journal
CHEMISTRY-AN ASIAN JOURNAL
Volume 13, Issue 17, Pages 2414-2417Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201800536
Keywords
asymmetric synthesis; organoboron compounds; palladium; stereospecific reaction; synthetic methods
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Funding
- JSPS KAKENHI [JP23655082, JP26288048, JP15H05811]
- Nikko Memorial Agency
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Suzuki-Miyaura coupling of nonbenzylic -(acylamino)alkylboron compounds with aryl halides is established. A Pd/PCy2Ph catalyst promotes the reaction efficiently at 145 degrees C. The reaction of enantioenriched -(acylamino)alkylboron compounds affords chiral 1-arylalkylamides in high enantiospecificity and inversion of configuration.
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