Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 24, Issue 29, Pages 7354-7357Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201801241
Keywords
allylation; C-C bond formation; nickel; quaternary; sustainable chemistry
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Funding
- University of Huddersfield
- Royal Society
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A totally catalytic nickel(0)-mediated method for base-free direct alkylation of allyl alcohols and allyl amines is reported. The reaction is selective for monoallylation, uses an inexpensive Ni-II precatalyst system, and requires no activating reagents to be present.
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