Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 24, Issue 43, Pages 11158-11165Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201801693
Keywords
electrochemistry; heterostructures; hydrogen evolution reaction; transition metals dichalcogenides; water splitting
Categories
Funding
- Australian Research Council (ARC) DECRA Grant [DE160100596]
- AIIM FOR GOLD Grant
Ask authors/readers for more resources
Transition-metal dichalcogenides (TMDs) are promising electrocatalysts toward the hydrogen evolution reaction (HER) in acid media, but they show significantly inferior activity in alkaline media due to the extremely sluggish water dissociation kinetics. Herein, CoSe2/MoSe2 heterostructures with CoSe2 quantum dots anchored on MoSe2 nanosheets are synthesized towards enhanced alkaline HER catalytic activity. The incorporation of CoSe2 is intended to construct additional water adsorption sites on the basal planes of MoSe2 to promote water dissociation. The CoSe2/MoSe2 heterostructures show substantially enhanced activity over MoSe2 and CoSe2 in 1 m KOH. The optimal overpotential required to reach a current density of 10 mAcm(-2) is merely 218 mV, which is more than 100 mV greater than that of MoSe2, which is by far the best performance demonstrated for precious-metal-free catalysts. Detailed analyses based on electrochemical testing demonstrate that the water adsorption and subsequent dissociation process is accelerated by CoSe2 species with rich edge sites; meanwhile, MoSe2 species provide sufficient active sites for the adsorption and combination of adsorbed hydrogen (H-center dot). These results provide an effective strategy for developing earth-abundant catalysts with high activity for the alkaline HER, and are of great significance to promote the practical application of alkaline water electrolysis.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available