Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 24, Issue 8, Pages 1801-1805Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201705391
Keywords
halogen bonding; organic luminescent materials; room-temperature phosphorescence; stimuli-response; switching material
Categories
Funding
- Ministry of Science and Technology of China [2017YFA0204503]
- National Natural Science Foundation of China [21503139, 21521062, 21673144]
- Beijing Natural Science Foundation of China [2162011]
- High-level Teachers in Beijing Municipal Universities in the Period of 13th Five-year Plan [IDHT20180517, CITTCD20180331]
- Youth Innovative Research Team of Capital Normal University
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Organic room-temperature phosphorescence (ORTP), when combined with external stimuli-responsive capability, is very attractive for sensors and bio-imaging devices, but remains challenging. Herein, by doping two beta-iminoenamine-BF2 derivatives (S-2CN and S-2I) into a 4-iodoaniline (I-Ph-NH2) crystalline matrix, the formation of S-2CN center dot center dot center dot I-Ph-NH2 and S-2I center dot center dot center dot I-Ph-NH2 halogen bonds leads to bright-red RTP emissions from these two host-guest doped crystals (hgDCs) with quantum efficiencies up to 13.43% and 15.96 %, respectively. Upon treatment with HCl, the competition of I-Ph-NH2 center dot HCl formation against S-2I center dot center dot center dot I-Ph-NH2 halogen bonding switches off the red RTP from S-2I/I-Ph-NH2 hgDCs, whereas the stable halogen-bonded S-2CN center dot center dot center dot I-Ph-NH2 ensures red RTP from S-2CN/I-Ph-NH2 hgDCs remains unchanged. A security protection luminescence pattern by using these different HCl-responsive RTP behaviors was designed.
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