4.6 Review

Photoredox Reactions of Quinones

Journal

CHEMISTRY-A EUROPEAN JOURNAL
Volume 24, Issue 60, Pages 15955-15964

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201801064

Keywords

C-H functionalization; natural products; photochemistry; quinones; redox reaction

Funding

  1. JSPS KAKENHI [JP16H06351, JP26810018]

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Photoredox reactions of quinones are reviewed, that enable C-H bond oxidation at the vicinity of the excited quinone carbonyl and concomitant reduction of the quinone under photoirradiation. Mechanistic insights on the benzo-, naphtho-, and anthraquinones are discussed. Also the potential utilities in organic synthesis are described.

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