Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 24, Issue 25, Pages 6586-6594Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201705232
Keywords
energy conversion; metal-organic frameworks; oxygen reduction reaction; supercapacitors; xerogels
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Funding
- DST, India [IITM/SERB/RRK/173]
- IIT Mandi [IITM/SG/NRT-58]
- MHRD
- CSIR, India
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Low cost, non-noble metal catalysts with a good oxygen reduction reaction (ORR) activity comparable to that of platinum and also having good energy storage properties are highly desirable but challenging. Several challenges are associated with the development of such materials. Herein, we demonstrate a new polycarboxyl-functionalised Fe-III-based gel material, synthesised following a solvothermal method and the development of its composite (Fe3O4/Fe/C) by annealing at optimised temperature. The developed composite displayed excellent electrocatalytic activity for the oxygen reduction reaction with an onset potential of 0.87 V (vs. RHE) and a current density value of -5 mA cm(-2), which are comparable with commercial 20 wt% Pt/C. In addition, as one of the most desirable properties, the composite exhibits a better methanol tolerance and greater durability than Pt/C. The same material was explored as an energy storage material for supercapacitors, which showed a specific capacitance of 245 Fg(-1) at a current density of 1 Ag-1. It is expected that this Fe3O4/Fe/C composite with a disordered graphitised carbon matrix will pave a horizon for developing energy conversion and energy storage devices.
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