Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 24, Issue 28, Pages 7114-7117Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201800543
Keywords
alkylarylation; charge-transfer complex; C-N bond activation; homogeneous catalysis; nickel
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Funding
- Anhui provincial Natural Science Foundation [1708085MB28]
- Fundamental Research Funds for the Central Universities
- CAS Interdisciplinary Innovation Team
- National Natural Science Foundation of China [21790333, 21672199]
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A nickel-catalyzed alkylarylation of active alkenes with tertiary benzylamines was achieved by charge-transfer-complex promoted C-N bond activation. The reaction proceeded through initial Ni-catalyzed C-N bond activation, followed by sequential radical addition, redox and proton abstraction with cleaved amine moiety in the absence of oxidant, and provides an efficient method to prepare various alkyl-substituted oxindoles and dihydroquinolinones in good yields.
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