Journal
CHEMISTRY LETTERS
Volume 47, Issue 8, Pages 1036-1039Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.180388
Keywords
La-Al2O3; NO-CO reaction; NOx
Categories
Funding
- JSPS KAKENHI from the Japan Society for the Promotion of Science (JSPS) [17H01341, 18K14051]
- Japanese Ministry of Education, Culture, Sports, Science, and Technology (MEXT) within the project Integrated Research Consortium on Chemical Sciences (IRCCS)
- Japanese Ministry of Education, Culture, Sports, Science, and Technology (MEXT) within the project Elements Strategy Initiative to Form Core Research Center
- JST-CREST project [JPMJCR17J3]
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Studies were carried out to explore catalytic NO-CO reactions promoted by La-loaded and unloaded Al2O3 supported Pd in both powder and cordierite monolithic honeycomb forms. La introduction significantly enhanced catalytic activity toward the NO-CO reaction. The results of in situ FT-IR studies suggest that the promotion effect of La is a consequence of efficient formation of surface nitrite species and their reactivity upon introduction of CO as a reactant.
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