Journal
CHEMISTRY LETTERS
Volume 47, Issue 8, Pages 1048-1050Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.180426
Keywords
Copper; Cross-coupling; Organosilane
Categories
Funding
- JST, ACT-C [JPMJCR12Z1]
- JSPS [18J12593, 17K19127]
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We report that simple aryl(trialkyl) silanes undergo crosscoupling reaction with alkyl (pseudo) halides in the presence of copper iodide/phenanthroline catalyst and cesium fluoride. Various aryl(trialkyl) silanes and alkyl electrophiles having iodine, bromine, chlorine, and tosyloxy group are applicable to the present reaction. Because such silanes are stable and readily accessible by catalytic C-H silylation, this protocol allows us to synthesize alkylarenes rapidly.
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