Journal
CHEMISTRY LETTERS
Volume 47, Issue 5, Pages 674-677Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.180143
Keywords
Alkyne; Arene; C-H Activation
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Funding
- JST, ACT-C [JPMJCR12Z1]
- JSPS [17K19127]
- Sumitomo Foundation [160752]
- Grants-in-Aid for Scientific Research [17K19127] Funding Source: KAKEN
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Palladium/carboxylic acid-catalyzed alkenylation of heteroarenes and electron-deficient arenes using alkynes underwent C(sp(2))-H bond activation in arene substrates to give the corresponding alkenylarenes straightforwardly. The versatility of this transformation is demonstrated by the double alkenylation of functionalized thiophenes and 5,6-difluorobenzothiadiazole with alkynes and provides a one-step access to vinylene-arylene-vinylene units.
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