Journal
CHEMISTRY LETTERS
Volume 47, Issue 4, Pages 472-474Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.171220
Keywords
Acridone; Pyrrolidine; Asymmetric Michael addition
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The rigid and planar acridone moiety was successfully linked with a chiral pyrrolidine template through an amide bond to develop a novel organocatalyst. This organocatalyst competently promotes the asymmetric Michael addition of cyclohexanone to nitroolefins with anisole, naphthalene, and heterocyclic aromatic rings under neat conditions. In this novel approach, the acridone moiety proved effective in chiral organocatalysis.
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