Journal
CHEMISTRY LETTERS
Volume 47, Issue 6, Pages 763-766Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.180201
Keywords
Cross-coupling reaction; Fe complex catalyst; Alkyl Grignard reagent
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Funding
- MEXT, Japan [JP16H01150]
- JSPS Japanese-German Graduate Externship from JSPS
- [JP25248025]
- [JP16H06039]
- Grants-in-Aid for Scientific Research [16H01150, 16H06039] Funding Source: KAKEN
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Iron-catalyzed cross-coupling reaction of alkyl halides with alkyl Grignard reagents by the combined use of cyclopentadienyl ligand and 1,3-butadiene additive is described. The reaction smoothly proceeds at room temperature using unactivated alkyl bromides and fluorides via non-radical mechanism, which is in sharp contrast with hitherto known Fe-catalyzed cross-coupling reactions of alkyl halides.
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