Angle dependence in slow photon photocatalysis using TiO2 inverse opals

The slow photon effect was studied by means of the photocatalytic degradation of stearic acid over TiO2 inverse opals. The comparison of the degradation rates over inverse opals with those obtained over disordered structures at different irradiation angles showed that the irradiation at the blue edge of the stopband leads to the activation of the effect, evidenced by an improvement factor of 1.8 +/- 0.6 in the reaction rate for irradiation at 40 degrees. The rigorous coupled-wave analysis (RCWA) method was employed to confirm the source of the enhancement; simulated spectra showed an enhancement in the absorption of the TiO2 matrix that composes the inverse opal at a 40 degrees irradiation angle, owing to an appropriate position of the stopband in relation to the absorption onset of TiO2. (C) 2018 Elsevier B.V. All rights reserved.