Journal
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
Volume 71, Issue -, Pages 1219-+Publisher
INT UNION CRYSTALLOGRAPHY
DOI: 10.1107/S2056989015017429
Keywords
crystal structure; rhenium(III); cluster; alkylcarboxylate complex; quadruple metal-metal bond; hydrogen bonding
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Funding
- Ministry of Education and Science of Ukraine [0111U000111]
- COST Action [CM 1105]
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The title compound, [Re-2(C3H7COO)(2)Cl-4{(CH3)(2)SO}(2)], comprises binuclear complex molecules [Re-Re = 2.24502 (13) angstrom] involving cis-oriented double carboxylate bridges, four equatorial chloride ions and two weakly bonded O atoms from dimethyl sulfoxide ligands in the axial positions at the Re-III atoms. In the crystal, molecules are linked into corrugated layers parallel to (101) by very weak C-H center dot center dot center dot Cl and C-H center dot center dot center dot O hydrogen-bonding interactions. C-H center dot center dot center dot Cl hydrogen bonding provides the links between layers to consolidate a three-dimensional framework.
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