Journal
CHEMICAL ENGINEERING RESEARCH & DESIGN
Volume 134, Issue -, Pages 497-506Publisher
INST CHEMICAL ENGINEERS
DOI: 10.1016/j.cherd.2018.04.030
Keywords
Gas hydrate; Gas separation; Hydrate decomposition; Gas recovery; Refrigerant gas
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Funding
- Japan Society for the Promotion of Science (JSPS) (JSPS KAKENHI) [JP16K06821]
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Many studies have been conducted on the application of hydrate-based gas separation to recover or reduce greenhouse-gas emissions. We evaluated the effects of hydrate-slurry decomposition conditions, specifically depressurization and heating, on gas recovery and separation, by using mixtures of refrigerants R22 or R134a with N-2 as models of a greenhouse gas and a low-pressure gas, respectively. The recoveries of R22 and R134a were assessed and N-2 was released preferentially during the earlier stage of decomposition, such that the highest N-2 recovery rate was obtained during that time span. In contrast, the recovery rates of the target gases increased gradually with time up to maximum values. Pressure and temperature had a minimal effect on the N-2 recovery rate, whereas the target gas-recovery rates were highly dependent on decomposition pressure and temperature values. The maximum separation factors were approximately 50 for R22 and 20 for R134a. A mechanism for the variation in separation factor is proposed, based on an analysis of gas generation as a function of decomposition time and fluid temperature. (C) 2018 Institution of Chemical Engineers. Published by Elsevier B.V. All rights reserved.
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