Journal
CHEMICAL ENGINEERING JOURNAL
Volume 352, Issue -, Pages 745-755Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2018.07.096
Keywords
Chiral polyaniline; Superhelical structure; Chirality; Multiple loss mechanisms; Microwave absorption
Categories
Funding
- National Natural Science Foundation of China (NSFC) [51503183]
- Key Program for International Science and Technology Cooperation Projects of Ministry of Science and Technology of China [2016YFE0125900]
- Zhejiang Province Natural Science Foundation of China [LQ14E030010]
- Program for Innovative Research Team of Zhejiang Sci-Tech University [15010039-Y]
- Zhejiang Top Priority Discipline of Textile Science and Engineering [2015KF07]
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Chiral polyaniline (PANI) with superhelical structure is successfully synthesized via in situ polymerization using chiral acid as dopant and self-assembly technique. The morphology and structure were characterized by scanning electron microcopy, transmission electron microscopy, fourier transform infrared spectra, circular dichroism, X-ray diffractometer and X-ray photoelectron spectra, which demonstrate polyaniline has chirality and superhelical structure. A possible formation process of the superhelical structure was also discussed. The microwave absorption properties of superhelical chiral PANI was investigated in the frequency range of 2-18 GHz. The results indicated that the superhelical chiral PANI exhibit substantially enhanced electromagnetic losses compared to conventional PANI. The minimum reflection loss (RL) of the superhelical chiral PANI can reach - 31.7 dB at 11.7 GHz, and the bandwidth less than -10 dB is 3.8 GHz with absorber thickness of 1.7 mm. The enhanced microwave absorbing property can be attributed to multi-loss mechanisms, good impedance matching and the cross-polarization effects resulting from the superhelical structure and chirality.
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