4.7 Article

An Fe(TCNQ)(2) nanowire array on Fe foil: an efficient non-noble-metal catalyst for the oxygen evolution reaction in alkaline media

Journal

CHEMICAL COMMUNICATIONS
Volume 54, Issue 18, Pages 2300-2303

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc09105b

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Funding

  1. National Natural Science Foundation of China [21575137]

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It is highly desirable to develop efficient and durable oxygen evolution reaction (OER) electrocatalysts. Herein, we report the in situ development of an Fe-(tetracyanoquinodimethane)(2) nanowire array on Fe foil (Fe(TCNQ)(2)/Fe) via a solution immersion method. As a non-noble-metal OER electrocatalyst, such Fe(TCNQ)(2)/Fe needs an overpotential of only 340 mV to drive a geometrical catalytic current density of 10 mA cm(-2) in 1.0 M KOH. Notably, it also shows strong long-term electrochemical durability capable of maintaining its catalytic activity for at least 110 h.

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