4.7 Article

Efficient visible light-driven water oxidation catalysts based on B-β-{BiW8O30} and unique 14-nuclear hetero-metal sandwich unit

Journal

CHEMICAL COMMUNICATIONS
Volume 54, Issue 6, Pages 674-677

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc06064e

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Funding

  1. National Natural Science Foundation of China [21571044, 21371042]
  2. Natural Science Foundation of Heilongjiang Province [ZD2015001, JJ2016JQ0037, B2017007]

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A sandwich tungstobismuthate with new topology based on {B-beta-BiW8O30}-cluster and unique 14-nuclear sandwich unit is reported as a high-efficiency visible light-driven water oxidation catalyst containing extended hetero-metal oxygen layer. At optimal conditions, the turn-over number (TON) of the title compound can reach 205.5 with O-2 yield of 32.88%.

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