4.7 Article

Pd-Catalyzed reductive heck reaction of olefins with aryl bromides for Csp(2)-Csp(3) bond formation

Journal

CHEMICAL COMMUNICATIONS
Volume 54, Issue 45, Pages 5752-5755

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc02571a

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Funding

  1. National Natural Science Foundation of China [21773210, 21603190, 21473160, 21376224]
  2. Zhejiang University of Technology and Qianjiang Scholar Program - Zhejiang Province

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We developed a Pd-catalyzed intermolecular reductive Heck reaction to construct Csp(2)-Csp(3) bonds between aryl bromides and olefins. Various styrene derivatives, acyclic and cyclic alkenes, were well tolerated to couple with varied aryl bromides in linear selectivity. Kinetic and deuterium labeling experiments suggested that i-PrOH provides a hydride through -H elimination.

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