Journal
CHEMICAL COMMUNICATIONS
Volume 54, Issue 50, Pages 6812-6815Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc01189c
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Funding
- National Natural Science Foundation of China [21722205]
- Project of Scientific and Technological Infrastructure of Suzhou [SZS201708]
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
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Herein a novel, elusive cyanotrifluoromethylthiolation of unactivated dialkyl-substituted alkynes is reported. Taking advantage of the intramolecular cyano migration strategy, the reaction proceeds stereoselectively to deliver E-olefinic products. A variety of tetrasubstituted trifluoromethylthiolated acrylonitriles are afforded in modest to good yields.
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