4.7 Article

Wavelength selective separation of metal ions using electroactive ligands

Journal

CHEMICAL COMMUNICATIONS
Volume 54, Issue 54, Pages 7507-7510

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc03371d

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Funding

  1. Center for Actinide Science and Technology (CAST), an Energy Frontier Research Center - U.S. Department of Energy, Office of Science, Basic Energy Sciences [DESC0016568]
  2. NIH [S10 OD021758-01A1]

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The separation of metal ions can be challenging because of similarities in charge density, size, and binding affinities. Here, we introduce a new photochemical separation strategy that relies on the intrinsically unique photophysical properties of metal ion complexes and the selective transformation of an electroactive ligand.

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