Journal
CHEMICAL COMMUNICATIONS
Volume 54, Issue 56, Pages 7794-7797Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc04027c
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Funding
- National NSF of China [21432005]
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The development of transition metal-catalyzed oxidative C-H/C-H cross-coupling between two (hetero)arenes to forge aryl-heteroaryl motifs under mild conditions is an appealing yet challenging task. Herein, we disclose a rhodium-catalyzed oxidative C-H/C-H cross-coupling reaction of an N-nitrosoaniline with a heteroarene under mild conditions. The judicious choice of the N-nitroso group as a directing group enables heightened reactivity. The coupled products could be transformed expediently to (2-aminophenyl)heteroaryl skeletons.
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