4.7 Article

Chemiluminescence of black phosphorus quantum dots induced by hypochlorite and peroxide

Journal

CHEMICAL COMMUNICATIONS
Volume 54, Issue 57, Pages 7987-7990

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc04513e

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Funding

  1. National Natural Science Foundation of China [21575093, 21505095]
  2. Science & Technology Department of Sichuan Province of China [2015JY0272]

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For the first time, black phosphorus quantum dots (BP QDs) were found to show chemiluminescence (CL) properties in the presence of hydrogen peroxide (H2O2) and hypochlorite (ClO-). Excited phosphorus oxides (HPO) resulting from the oxidation of BP QDs account for CL emission. Taking triacetone triperoxide (TATP) as an example, the potential application of a new CL system was evaluated. This work sheds new light on the characteristics and broader applications of black phosphorus (BP).

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