4.7 Article

Heterojunctions of silver-iron oxide on graphene for laser-coupled oxygen reduction reactions

Journal

CHEMICAL COMMUNICATIONS
Volume 54, Issue 57, Pages 7900-7903

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc03136c

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Funding

  1. Ministry of Science and Technology, Taiwan [106-2113-M-110-010]
  2. NSYSU-NUK Joint Research Project [NSYSU-NUK 107-P005]

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We report a two-step hybridization of N-doped graphene and Ag-decorated Fe2O3 hematite to realize a balanced oxygen adsorption/desorption equilibrium and a laser-coupled ORR (LORR). The stable plateau currents with n values of 3.9 in a wide potential range (0.2-0.7 V) and 7.5% peroxide inhibition of the LORR are found to be directly associated with the Ag/Fe2O3 heterojunction, where interactions of semiconductor band gap excitation and plasmonic resonance-induced hot electrons are proposed to occur.

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