4.7 Article

Chirality sensing of choline derivatives by a triple anion helicate cage through induced circular dichroism

Journal

CHEMICAL COMMUNICATIONS
Volume 54, Issue 53, Pages 7378-7381

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc03883j

Keywords

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Funding

  1. National Natural Science Foundation of China [21701132, 21772154, 21402151, 21325102]
  2. Education Department of Shaanxi [16JS113]
  3. Northwest University [2018212]
  4. China Postdoctoral Science Foundation [2016M602849]

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Chirality sensing of choline derivatives is achieved by a self-assembled, racemic triple anion helicate cage which exhibits induced circular dichroism (ICD) upon encapsulation of a chiral guest. The host-guest interactions were illustrated by NMR, crystal structure, CD and DFT calculations. The absolute configurations and ee values were determined by ICD.

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