Journal
JOURNAL OF NEW MATERIALS FOR ELECTROCHEMICAL SYSTEMS
Volume 18, Issue 3, Pages 131-135Publisher
ECOLE POLYTECHNIQUE MONTREAL
DOI: 10.14447/jnmes.v18i3.358
Keywords
LiCoO2; Carbon conductive additives; Graphene nanosheets; Lithium-ion batteries
Funding
- Fundamental Research Funds for the Central Universities [CDJZR13130027]
- National Natural Science Foundation of China [51172293]
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Carbon black(CB), multi-walled carbon nanotubes(CNTs) and graphene nanosheets(GNs) were employed as carbon conductive additives for LiCoO2(LCO). X-ray diffraction, transmission electron microscopy and scanning electron microscopy were used to characterize the crystal structure and morphology of samples. And the specific surface area and porosity structure of the three kinds of carbon conductive additives were measured by N-2 adsorption-desorption. To investigate the effect on the electrochemicdl reaction activity, galvanostatic discharge-charge experiments showed that the composite of LCO-GNs exhibited the highest specific capacity of 167mAh/g at 0.1C and 123 mAh/g at 1 C rate. The flexible wrapping of GNs and bridging nearby LCO particles together were found to enhance electrical conductivity most effectively.
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