Journal
CHEMICAL COMMUNICATIONS
Volume 54, Issue 2, Pages 188-191Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc08191j
Keywords
-
Categories
Funding
- Conacyt [CB-2015-252356, CB-2015-254742, EDOMEX-2011-COI-165873]
- CONICYT-Programa de Cooperacion Internacional [REDES 150042]
- Conacyt
Ask authors/readers for more resources
Herein we propose a general mechanism for the racemization of [n] helicenes up to n = 24. It is a concerted process for n = 4-7, but a multi-step mechanism is followed for n >= 8, involving 2n - 14 intermediates. The changes in the barriers are a delicate consequence of the steric hindrance and the pi-interactions.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
