Journal
CHEMICAL COMMUNICATIONS
Volume 54, Issue 44, Pages 5598-5601Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc03083a
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Funding
- National Science Foundation of China [51573140, 21734007]
- Hubei Province [2017CFA002]
- special funds for basic scientific research services in central colleges and universities [2042017kf0247]
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Two isomers of mm-TPE(PI)(2) and pp-TPE(PI)(2), constructed by the two same aromatic blocks of tetraphenylethene and phenanthro[9,10-d]imidazole, exhibit totally different mechanoluminescence, as a result of the ignorable different linkage positions on the tetraphenylethene moiety. Detailed analysis and theoretical calculations demonstrate the structure-packing-property relationship of organic mechanoluminescent luminogens, with the emphasis on the important role of molecular packing in the solid state.
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