Journal
CHEMICAL COMMUNICATIONS
Volume 54, Issue 27, Pages 3323-3326Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc08927a
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- DFG IRTG
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A significant decrease in the amount of the sacrificial electron donor triethanolamine (TEOA) required for the homogeneous photocatalytic reduction of CO2 using rhenium-based catalytic systems can be achieved by adding small quantities of 1,8-diazabicyclo-[5.4.0]undec-7-ene (DBU) to the reaction mixture. The turnover numbers (TONs) and frequencies (TOFs) measured for the reactions described herein are even higher than those observed in reaction mixtures containing high concentrations of TEOA. Furthermore, replacing TEOA with DBU in the solutions of Re(i)/Ru(ii) mixed catalytic systems leads to a doubling of the values of TON and TOF.
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