Journal
CHEMICAL COMMUNICATIONS
Volume 54, Issue 51, Pages 6999-7002Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc03189d
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Funding
- Ministry of Environment and Energy, Ministry of Science and Education, Environmental Protection and Energy Efficiency Fund of the Republic of Croatia
- Croatian Science Foundation project New materials for energy storage''
- Croatian Science foundation [4744]
- Adris foundation
- NSERC [RGPIN-2017-06467]
- NSERC E. W. R. Steacie Memorial Fellowship [SMFSU 507347-17]
- Defense Threat Reduction Agency [HDTRA1-18-1-0003]
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The use of a dodecanuclear zirconium acetate cluster as a precursor enables the rapid, clean mechanochemical synthesis of high-microporosity metal-organic frameworks NU-901 and UiO-67, with surface areas up to 2250 m(2) g(-1). Real-time X-ray diffraction monitoring reveals that mechanochemical reactions involving the conventional hexanuclear zirconium methacrylate precursor are hindered by the formation of an inert intermediate, which does not appear when using the dodecanuclear acetate cluster as a reactant.
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