4.7 Article

Enhancement of metal-metal interactions inside a large-cavity synthetic host in water

Journal

CHEMICAL COMMUNICATIONS
Volume 54, Issue 17, Pages 2169-2172

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc00593a

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Funding

  1. National Natural Science Foundation of China [21472143, 21372183, 21604066]
  2. Thousand Youth Talents Program of China

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The encapsulation of a series of metal-terpyridyl complexes in cucurbit[10]uril (CB[10]) in water is described. A strong enhancement of metal-metal and p-p interactions is observed due to double confinement in the large cavity. Furthermore, a linear supramolecular polymer featuring host-enhanced metallophilic interactions in water can be prepared.

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