Journal
CHEMICAL COMMUNICATIONS
Volume 54, Issue 50, Pages 6832-6834Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc02535e
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- La Trobe University
- Australian Research Council [FT16010007]
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Stable difluorogold(iii) complexes can be easily synthesized either via oxidation of N-ligated cationic Au(i) precursors using XeF2 or from tricationic Au(iii) precursors by displacement of the N-ligands using fluoride from economical KF. X-ray crystallographic studies of the bisimidazole ligated derivative shows the shortest Au-F bond known in a gold complex.
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