Journal
CHEMICAL COMMUNICATIONS
Volume 54, Issue 48, Pages 6120-6123Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc02433b
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Funding
- University of Auckland (Frederick Douglas Brown Postgraduate Science Research Scholarship)
- Rutherford Discovery Fellowship - NZ government
- NZ synchrotron group
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The first X-ray structures of adducts formed between a Ru-II(N-heterocyclic carbene)(eta(6)-p-cymene) compound and a protein are reported. Coordination to the protein induced the cleavage of the cymene ligand and EPR spectroscopy demonstrated the oxidation of the Ru centre.
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