4.7 Article

A green route to a novel hyperbranched electrolyte interlayer for nonfullerene polymer solar cells with over 11% efficiency

Journal

CHEMICAL COMMUNICATIONS
Volume 54, Issue 5, Pages 563-566

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc08604k

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Funding

  1. National Science Fund for Distinguished Young Scholars [51425304]
  2. National Natural Science Foundation of China [51673091, 51703091, 51473075, 51673092, 21762029]
  3. Doctoral Scientific Research Foundation of Nanchang Hangkong University [EA201702484]

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A novel environmentally-friendly hyperbranched electrolyte PNSO3Na organic interfacial layer has been synthesized; this can tune the interfacial energy alignment and induce the upper active layer to form a bi-continuous nano-micro phase separation face-on orientation. Based on a PBDB-T:ITIC active layer, the device with a ZnO/PNSO3Na ETL exhibits a high efficiency of 11.2%.

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