Journal
CHEMICAL COMMUNICATIONS
Volume 54, Issue 47, Pages 5976-5979Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc02381f
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Funding
- National Natural Science Foundation of China [21573252, 21433011, 91527303, 21725306]
- National Basic Research Program [2017YFA024702]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB12020100]
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A heterogeneous nucleation and growth method is reported to synthesize imine-linked covalent organic frameworks (COFs). Excellent crystallinity and a high surface area are obtained. The introduction of heterogeneous nuclei suppresses the fast precipitation of amorphous structures at the early stage while promoting the crystallization of COFs during the growth process.
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