Journal
CHEMICAL COMMUNICATIONS
Volume 54, Issue 16, Pages 1980-1983Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc00187a
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New Raman spectra of Na2S dissolved in hyper-concentrated NaOH(aq) and CsOH(aq) cast serious doubt on the widely-assumed existence of S2- (aq). To avoid conceptual and practical problems with sulfide equilibria in numerous applications, S2- (aq) should be expunged from the chemical literature. Thermodynamic databases involving sulfide minerals also need careful revision.
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