4.7 Article

Crystalline and permanently porous porphyrin-based metal tetraphosphonates

Journal

CHEMICAL COMMUNICATIONS
Volume 54, Issue 4, Pages 389-392

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc07766a

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Funding

  1. Deutsche Forschungsgemeinschaft [SPP 1928, STO 643/11-1, WA 1116/30-1]

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The new porphyrin-based tetraphosphonic acid (Ni-H8TPPP) was employed in the synthesis of four isostructural MOFs of composition [M(Ni-H6TPPP)(H2O)], denoted CAU-29 (M = Mn, Co, Ni, Cd). Ni-CAU-29 was thoroughly characterized regarding its thermal and chemical stability as well as for proton conductivity.

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