4.7 Article

Highly selective and efficient reduction of CO2 to CO on cadmium electrodes derived from cadmium hydroxide

Journal

CHEMICAL COMMUNICATIONS
Volume 54, Issue 43, Pages 5450-5453

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc02055h

Keywords

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Funding

  1. National Natural Science Foundation of China [21525316, 21673254]
  2. Ministry of Science and Technology of China [2017YFA0403003]
  3. Chinese Academy of Sciences [QYZDY-SSW-SLH013]

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A non-noble cadmium electrode was synthesized via an electrolysis strategy, which can electroreduce carbon dioxide into carbon monoxide with high selectivity and efficiency. The partial current density for CO can reach up to 59.0 mA cm(-2) at a Faradaic efficiency of 99.2% using 1-butyl-3-methylimidazolium hexafluorophosphate/acetonitrile as the electrolyte.

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