Journal
CHEMICAL COMMUNICATIONS
Volume 54, Issue 40, Pages 5086-5089Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc01707g
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Funding
- DFG [KO 2875/6-1]
- Humboldt foundation
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Despite the potential of silver to mediate synthetically valuable cross-coupling reactions, the operating mechanisms have remained unknown. Here, we use a combination of rapid-injection NMR spectroscopy, electrospray-ionization mass spectrometry, and quantum chemical calculations to demonstrate that these transformations involve argentate(I) and (III) complexes as key intermediates.
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