4.7 Article

Metallophthalocyanine-based redox active metal-organic conjugated microporous polymers for OER catalysis

Journal

CHEMICAL COMMUNICATIONS
Volume 54, Issue 35, Pages 4465-4468

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc01291a

Keywords

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Funding

  1. Department of Science & Technology (DST), New Delhi, India [PDF/2016/002324]
  2. DST, Govt. of India [MR-2015/001019, TRC-DST/C.14.10/16-2724]
  3. JNCASR

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We report the design and synthesis of two Co2+ and Zn2+ phthalocyanine (PC)-based redox active metal-organic conjugated microporous polymers (MO-CMP), CoCMP and ZnCMP, respectively, obtained by a Schiff base condensation reaction. CoCMP, where Co2+ is stabilized by N4-coordination of PC, has shown stable and efficient electrocatalytic activity towards the OER with a low overpotential of 340 mV.

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