Journal
CHEMICAL COMMUNICATIONS
Volume 54, Issue 5, Pages 452-455Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc08428e
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- PRESTO from JST [JPMJPR1442]
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Visible-light irradiation (lambda < 600 nm) of commercially-available CdS in alcohol successfully promotes hydrogenation of azobenzene to hydrazobenzene with more than 95% selectivity. This is promoted by strong adsorption of azobenzene to the photoformed zerovalent Cd species adjacent to the surface S vacancies on CdS; this leads to efficient reduction to hydrazobenzene.
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