Journal
CHEMICAL COMMUNICATIONS
Volume 54, Issue 9, Pages 1101-1104Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc07611h
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Funding
- United States Department of Energy (Basic Energy Science, Catalysis Science Program) [DE-SC0006587]
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The aerobic photochemical oxidation of benzylamine was carried out on the ternary oxides CuWO4 and BiVO4 as a test proton-coupled-electron-transfer reaction in acetonitrile. Both oxides give the coupled imine product, N-benzylidenebenzylamine, in near quantitative (98-99%) yield, with rate constants of 0.34 h(-1) g(-1) and 0.70 h(-1) g(-1) for CuWO4 and BiVO4, respectively.
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