4.7 Article

A porous triptycene-based covalent polymer stabilized binary metal sulfide for enhanced hydrogen evolution under visible light

Journal

CHEMICAL COMMUNICATIONS
Volume 54, Issue 27, Pages 3391-3394

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc00665b

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Funding

  1. National Natural Science Foundation of China [21703019, 51702025]
  2. Natural Science Foundation of Jiangsu Province [BK20150259, BK20160277]

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A novel triptycene-based covalent polymer (TCP) with a high surface area was constructed through the Suzuki coupling reaction. A very high photocatalytic H-2 production rate of 50 670 mu mol h(-1) g(-1) and superior photostability were achieved due to the intimate synergistic interactions between the TCP and Cd0.5Zn0.5S.

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