4.7 Article

Cu(II) coordination polymers with nitrogen catenation ligands for efficient photocatalytic water oxidation

Journal

CHEMICAL COMMUNICATIONS
Volume 54, Issue 38, Pages 4794-4797

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc02359j

Keywords

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Funding

  1. Ministry of Science and Technology of China [2017YFA0206903, 2014CB239402]
  2. National Natural Science Foundation of China [91427303, 21390404]
  3. Strategic Priority Research Program of Chinese Academy of Science [XDB17000000]
  4. Key Research Program of Frontier Sciences of the Chinese Academy of Sciences [QUZDY-SSW-JSC029]

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A Cu(II) coordination polymer, [Cu(tza)(2)](n) (Htza, tetrazole-1-acetic acid), was investigated as an efficient water oxidation catalyst in the well-established Ru(bpy)(3)(2+)/S2O82- (bpy = 2,2'-bipyridine) photocatalytic system. The turnover frequency (TOF) was measured to be 1.68 s(-1), which is the highest among all reported copper-based photocatalytic water oxidation systems.

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