4.7 Article

Fluorescence/phosphorescence-conversion in self-assembled organic microcrystals

Journal

CHEMICAL COMMUNICATIONS
Volume 54, Issue 46, Pages 5895-5898

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc01791c

Keywords

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Funding

  1. National Natural Science Foundation of China [21703148, 21703268]
  2. National Key Research and Development Plan of China [2016YFB0400700]
  3. Natural Science Foundation of Jiangsu Province [BK20170330]
  4. Collaborative Innovation Center of Suzhou Nano Science and Technology (CIC-Nano)
  5. Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
  6. 111 Project of The State Administration of Foreign Experts Affairs of China

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Organic molecules of DIDB can inherently assemble into fluorescent green-emissive microwires with a low photoluminescence quantum efficiency (PLQY) of 1.0%. Impressively, by doping DIDB into the nonluminous 4-iodobenzonitrile crystal matrix with a molar ratio of 1 : 100, phosphorescent yellow-emissive microwires with a much higher PLQY of 50.5% are obtained.

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